By Frederic Lantelme, Visit Amazon's Henri Groult Page, search results, Learn about Author Central, Henri Groult,
Molten salts and fused media give you the key homes and the idea of molten salts, in addition to features of fused salts chemistry, aiding you generate new principles and purposes for fused salts. Molten Salts Chemistry: From Lab to Applications examines how and thermal houses of molten salts, and usually low vapour strain are good tailored to hot temperature chemistry, permitting speedy response premiums. It additionally explains how their skill to dissolve many inorganic compounds similar to oxides, nitrides, carbides and different salts make molten salts excellent as solvents in electrometallurgy, steel coating, remedy of by-products and effort conversion. This publication additionally experiences more moderen purposes of molten salts together with fabrics for strength garage akin to carbon nano-particles for effective tremendous capacitors, excessive skill molten salt batteries and for warmth shipping and garage in sunlight crops. furthermore, as a result of their excessive thermal balance, they're regarded as excellent applicants for the improvement of more secure nuclear reactors and for the therapy of nuclear waste, specifically to split actinides from lanthanides through electrorefining.
- Explains the speculation and homes of molten salts to assist scientists comprehend those precise liquids
- Provides a terrific advent to this increasing field
- Illustrated textual content with key real-life functions of molten salts in synthesis, power, nuclear, and steel extraction
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Additional resources for Molten salts chemistry: from lab to applications
Chem. Chem. , 11, 11501–11506. , Binder, K. (2002). Dynamics of sodium in sodium disilicate: channel relaxation and sodium diffusion. Phys. Rev. , 88, 125502. , Barhoun, A. (2009). Transport in molten LiF-NaF-ZrF4 mixtures: a combined computational and experimental approach. J. , 130, 61–66. , Groult, H. (2012). Structural effects on the electrical conductivity of molten fluorides: comparison between LiF-YF3 and LiF-NaF-ZrF4. J. , 134, 44–48. , Thiaudie`re, D. (2004). A new cell for high temperature EXAFS measurements in molten rare earth fluorides.
Nevertheless, the effect of the nature of the alkali in molten mixtures is quite visible on Raman spectra and has been explored in detail because of its strong influence on the distribution of coordination numbers. The decrease of the bandwidths with the increase of the cation size has been explained by different authors : the cation–anion proximity due to the decreasing size and increasing electrostatic field of the cation slightly modifies the vibrational levels of energy, leading to some enlargements of the bands due to a distribution of environments.
Phys. Rev. , 88, 125502. , Barhoun, A. (2009). Transport in molten LiF-NaF-ZrF4 mixtures: a combined computational and experimental approach. J. , 130, 61–66. , Groult, H. (2012). Structural effects on the electrical conductivity of molten fluorides: comparison between LiF-YF3 and LiF-NaF-ZrF4. J. , 134, 44–48. , Thiaudie`re, D. (2004). A new cell for high temperature EXAFS measurements in molten rare earth fluorides. Nucl. Instrum. Methods Phys. Res. B, 226, 447–452. , Zanghi, D. (2007). Lanthanide and actinide speciation in molten fluorides: a structural approach by NMR and EXAFS spectroscopies.